Liquid-Liquid Separation (Solvent Extraction)

Crud

also known as rag layer · interfacial gunk · goo

Crud is a mechanically stable dispersion of fine solids — sub-micron silica, iron hydroxide colloids, gypsum fines or organic degradation products — held at the liquid–liquid interface. Because those solids are wetted partially by both phases, they lodge at the boundary instead of reporting to either one, forming a film that physically separates the phases. Crud is distinct from bulk emulsion, which breaks when agitation stops.

Why it matters in practice

Crud degrades every part of a circuit at once: phase disengagement slows, organic inventory balloons because crud traps several times its own volume in organic, entrainment losses rise, and extraction efficiency drifts down. Prevention (clean feed, controlled mixing energy, scheduled organic regeneration) is far cheaper than treatment.

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Related terms

Reference entry GL-CRUD. Definitions on this page describe engineering practice in hydrometallurgical process design; they are not a substitute for test work on your own material.

Working with Crud?

Send feed material, throughput and medium. An engineer replies with a preliminary configuration and the sizing reasoning attached.