Liquid-Liquid Separation (Solvent Extraction)

Extractant

also known as reagent · extraction reagent

The extractant is the functional molecule in the organic phase, typically a few to about thirty volume percent of the organic, dissolved in a diluent. Acidic extractants such as organophosphorus acids and oximes exchange a proton for a metal cation; amine extractants form ion pairs with anionic metal complexes. Each family has its own pH window and selectivity pattern.

Why it matters in practice

Extractant choice fixes the circuit's pH operating point, its stripping chemistry and its selectivity, and therefore the whole flowsheet around it. Because the extractant is also a significant recurring cost, its loading capacity directly determines the organic flow rate and hence the size of every contactor in the circuit.

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Equipment referenced in this entry

Related terms

Reference entry GL-EXTRACTANT. Definitions on this page describe engineering practice in hydrometallurgical process design; they are not a substitute for test work on your own material.

Working with Extractant?

Send feed material, throughput and medium. An engineer replies with a preliminary configuration and the sizing reasoning attached.